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Atomic Structure

Reference: NCERT Class 9-12, Lucent GK

1. Dalton's Atomic Theory & Bohr's Model

Dalton's Atomic Theory (1808)

John Dalton proposed that:

Postulate Status Today
Matter is made of indivisible atoms Partially True (atoms divisible)
Atoms of a given element are identical in mass and properties False (due to isotopes)
Atoms cannot be created or destroyed True in chemical reactions
Atoms combine in simple ratios to form compounds True
Chemical reactions involve rearrangement of atoms True

This theory laid the foundation but was later modified after discovery of electrons, protons, and neutrons.

Bohr's Model of Atom (1913)

Feature Description
Nucleus Contains positively charged protons and neutral neutrons
Electrons Revolve in fixed circular paths (called shells or energy levels) around nucleus
Energy Levels (Shells) K, L, M, N... (n = 1, 2, 3, ...)
Energy Absorption/ Emission Electrons jump to higher/lower shells by absorbing/releasing energy (as photons)

Formula for energy levels: Eₙ = –13.6 eV/n² (for hydrogen)

Key Models of the Atom

Model Scientist Description
Dalton's Model John Dalton (1803) Atom as an indivisible solid sphere
Thomson's Model J.J. Thomson (1897) "Plum pudding" model: positive sphere with embedded electrons
Rutherford's Model Ernest Rutherford (1911) Atom has a dense, positive nucleus with electrons orbiting around it
Bohr's Model Niels Bohr (1913) Electrons move in fixed energy levels (shells)
Quantum Model Erwin Schrödinger Electrons exist in probability clouds (orbitals)

This shows the evolution of atomic theory from solid spheres to quantum mechanical models.

2. Atomic Number and Mass Number

Term Symbol Definition Example (Carbon)
Atomic Number Z Number of protons (or electrons in neutral atom) Z = 6
Mass Number A Total number of protons + neutrons in nucleus A = 12 (6p + 6n)
Neutrons n = A – Z Number of neutrons n = 6

3. Isotopes and Isobars

Isotopes

Definition Example
Atoms of the same element (same Z) with different mass numbers (A) ₁H¹, ₁H² (Deuterium), ₁H³ (Tritium)
Same chemical properties, different physical properties Used in nuclear medicine, tracing, etc.

All isotopes have same number of protons but different neutrons.

Isobars

Definition Example
Atoms with same mass number (A) but different atomic numbers (Z) ₆C¹⁴ and ₇N¹⁴
Different elements with different properties Occur due to equal sum of protons + neutrons

4. Quick Facts

  • The value of G was first measured by Henry Cavendish in 1798
  • g on Moon ≈ 1/6th of Earth's gravity (1.62 m/s²)
  • Escape velocity from Earth's surface ≈ 11.2 km/s
  • Gravitational force is the weakest fundamental force
  • Satellites in geostationary orbit have orbital period = Earth's rotation period (24 hrs)
  • Weightlessness occurs when the only force acting is gravity (free-fall)
  • Electron was discovered by J.J. Thomson
  • Proton was discovered by E. Goldstein
  • Neutron was discovered by James Chadwick
  • Nucleus was discovered by Ernest Rutherford
  • Mass of electron ≈ 1/1836 of proton
  • Bohr’s model applies best to Hydrogen-like atoms
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